Studies on structure of sapogenins from pod of Gleditsia sinensis
- VernacularTitle:皂角皂苷元化学成分研究
- Author:
Xiaolan CHEN
;
Lingbo QU
;
Weicheng HAN
;
Jiyang WANG
;
- Publication Type:Journal Article
- Keywords:
pod of Gleditsia sinensis Lam;
3 hydroxy 12 oleanen 28 oic acid;
3, 16 dihydroxy 12 oleanen 28 oic acid
- From:
Chinese Traditional and Herbal Drugs
1994;0(03):-
- CountryChina
- Language:Chinese
-
Abstract:
Object To study on the structure of sapogenins from pod of Gleditsia sinensis Lam Methods Pod of G. sinensis was extracted with solvents and the constituents in the extraction isolated, after hydrolised completely, with the aid of flash chromatography to obtain 2 gledgenins Results The structures of the 2 gledgenins were proved to be 3 hydroxy 12 oleanen 28 oic acid and 3, 16 dihydroxy 12 oleanen 28 oic acid respectively as shown by IR, NMR, MS and crystallographic data The structures were further verified by acylation, methylation and followed by reaction with 3, 5 dinitro benzoyl chloride Conclusion New crystalline derivatives were obtained to provide further evidence of their structures
