Preparation of Reactive Formaldehyde Fluorescent Probe and Its Application in Rapid and Sensitive Detection of Formaldehyde in Food
10.19756/j.issn.0253-3820.251151
- VernacularTitle:反应型甲醛荧光探针的制备及其用于食品中甲醛的快速灵敏检测
- Author:
Jie-Ru MIAO
1
;
Qiang ZHANG
;
Yan LU
Author Information
1. 天津理工大学材料科学与工程学院,天津市光电材料与器件重点实验室,教育部显示材料与光电器件重点实验室,天津 300384
- Keywords:
Fluorescentprobe;
Formaldehyde;
Reactiveprobe;
Foodsafety
- From:
Chinese Journal of Analytical Chemistry
2025;53(11):1870-1878,中插30-中插37
- CountryChina
- Language:Chinese
-
Abstract:
Residual formaldehyde(FA)in environmental water samples,certain aquatic products,vegetables,and other food items poses a severe threat to environmental safety and human health.Therefore,the rapid,sensitive and selective detection of FA is very essential for food safety and environmental protection.In this work,a new 1,8-naphthalimide-based fluorescent probe NIPh for FA detection was synthesized by using hydrazide group as a reactive site for FA and naphthalimide as a fluorophore.Based on the photoinduced electron transfer(PET)process,the prepared probe NIPh showed a remarkable fluorescence lighting-up response towards FA in aqueous medium with high selectivity,fast response(within 4 min)and a low limit of detection(0.16 μmol/L).Further,the probe NIPh was also successfully applied as optical probe to detection of FA in cabbage,enoki mushroom,pond and tap water samples,with recoveries over 96%,and relative standard deviations less than 4%,demonstrating tremendous potential in FA monitoring in the field of food industry and environment.