An indirect square polarographic method was established f or the determination of ascorbic acid in pharmaceuticals using the oxidation-re duction action between Cu2+ and ascorbic acid. There was a reduction wav e of Cu2+ at about -0.24 V in buffer solution of NH3-NH4 Cl. The quantities of ascorbic acid is determination according to the decrement of peak heights when ascorbic acid was added. The linear range for ascrobic acid was 2.0×10-6~3.0×10-4 mol/L. Ascorbic acid in Vitami n C tablets was determined, the relative standard deviation is 2.9%.