1.Studies on dihydroflavonol glycosides from rhizome of Smilax glabra.
Jiu-zhi YUAN ; De-qiang DOU ; Ying-jie CHEN ; Wei LI ; Koike KAZUO ; Nikaido TAMOTSU ; Xin-sheng YAO
China Journal of Chinese Materia Medica 2004;29(9):867-870
OBJECTIVETo investigate the chemical constituents from the rhizomes of Smilax glabra.
METHODThe compounds were isolated by column chromatography with silica gel, Diaion HP-20 and ODS as packing materials, and HPLC. Their structures were determined on the basis of their spectral evidence.
RESULT5 dihydro-flavonol glycosides were identified as: astilbin (1), neoastilbin (2), isoastilbin (3), neoisoastilbin (4), (2R, 3R)-taxifolin-3'-O-beta-D-pyranglucoside (5).
CONCLUSIONCompounds 2, 4, 5 were isolated from this plant for the first time.
Flavonols ; chemistry ; isolation & purification ; Glucosides ; chemistry ; isolation & purification ; Plants, Medicinal ; chemistry ; Quercetin ; analogs & derivatives ; chemistry ; isolation & purification ; Rhizome ; chemistry ; Smilax ; chemistry ; Stereoisomerism
2.Chemical investingation of Chinese mangrove Sonneratia apetala II.
Qing-fei JI ; Wen-han LIN ; Jun LI ; Wei LI ; Koike KAZUO ; Nikaido TAMOTSU ; Hong-zheng FU
China Journal of Chinese Materia Medica 2005;30(16):1258-1260
OBJECTIVEIsolation and structural elucidation of the constituents of China mangrove Sonneratia apetala.
METHODchromatography methods were used for isolation of compounds, spectroscopic methods were used for structural identifyication.
RESULTseven known compounds named (+/-) symgaresinol, betulinic acid, lupeol, lupeone, stigmast-5-ene-3beta, 7alpha-diol, beta-alpha myrin hexadecaneate, physcoion were isolated.
CONCLUSIONthese known compouns were unreported previously from this plant.
Magnoliopsida ; chemistry ; Pentacyclic Triterpenes ; Plants, Medicinal ; chemistry ; Triterpenes ; chemistry ; isolation & purification