The effect of 4,4'-bis(N,N-diethylamino) benzophenone on the degree of conversion in liquid photopolymer for dental 3D printing.
- Author:
Du Hyeong LEE
1
;
Hang Nga MAI
;
Jin Chul YANG
;
Tae Yub KWON
Author Information
- Publication Type:Original Article
- Keywords: Photopolymer; Photointiator; Degree of conversion, 4,4'-bis(N,N-diethylamino)benzophenone; 3D Printing
- MeSH: Glycerol; Incidence; Polymerization; Polymers; Spectrum Analysis
- From:The Journal of Advanced Prosthodontics 2015;7(5):386-391
- CountryRepublic of Korea
- Language:English
- Abstract: PURPOSE: The purpose of this preliminary study was to investigate the effects of adding 4,4'-bis(N,N-diethylamino) benzophenone (DEABP) as a co-initiator to a binary photoinitiating system (camphorquinone-amine) to analyze on the degree of conversion (DC) of a light-cured resin for dental 3D printing. MATERIALS AND METHODS: Cylindrical specimens (N=60, n=30 per group, o5 mm x 1 mm) were fabricated using bisphenol A glycerolate dimethacrylate (BisGMA) both with and without DEABP. The freshly mixed resins were exposed to light in a custom-made closed chamber with nine light-emitting diode lamps (wavelength: 405 nm; power: 840 mW/cm2) for polymerization at each incidence of light-irradiation at 10, 30, 60, 180, and 300 seconds, while five specimens at a time were evaluated at each given irradiation point. Fourier-transform infrared (FTIR) spectroscopy was used to measure the DC values of the resins. Two-way analysis of variance and the Duncan post hoc test were used to analyze statistically significant differences between the groups and given times (alpha=.05). RESULTS: In the DEABP-containing resin, the DC values were significantly higher at all points in time (P<.001), and also the initial polymerization velocity was faster than in the DEABP-free resin. CONCLUSION: The addition of DEABP significantly enhanced the DC values and, thus, could potentially become an efficient photoinitiator when combined with a camphorquinone-amine system and may be utilized as a more advanced photopolymerization system for dental 3D printing.
