Analysis of Organophosphate Esters in Dust, Soil and Sediment Samples Using Gas Chromatography Coupled with Mass Spectrometry
10.3724/SP.J.1096.2014.31165
- VernacularTitle:气相色谱/质谱法检测灰尘、土壤和沉积物中有机磷酸酯
- Author:
Jianxia LU
;
Wen JI
;
Shengtao MA
;
Zhiqiang YU
;
Zhao WANG
;
Han LI
;
Guofa REN
;
Jiamo FU
- Publication Type:Journal Article
- Keywords:
Organophosphate flame retardant;
Organophosphate esters;
Gas chromatograph coupled with mass spectrometry;
Soil;
Sediment;
Dust
- From:
Chinese Journal of Analytical Chemistry
2014;(6):859-865
- CountryChina
- Language:Chinese
-
Abstract:
Background contamination is a major problem in the analysis of organophosphate esters (OPEs). In this study, the possible sources of OPEs pollution were screened and several different ways were applied to minimize the blank contamination. Under the strict quality control measures, the cleanup efficiency of different solid phase extraction (SPE) was investigated for OPEs in different environmental matrices. A method was developed for the detection of 7 OPEs in dust, soil and sediment samples by gas chromatograph coupled with mass spectrometry ( GC / MS). Target compounds were extracted by hexane:dichloromethane (1 : 1, V/ V) followed by aminopropyl silica gel SPE column cleanup for dust, and target compounds in soil and sediment were Soxhlet extracted and cleanuped by two-step SPE. The results showed that the aminopropyl silica gel SPE column displayed the best purification performance among the three employed columns. Instrumental detection limits among the 7 OPEs ranged from 2. 5 to 25. 8 μg / L, and the method limits of quantification (MLOQs) in dust and soil sample ranged from 1. 4 to 15. 7 ng / g and 0. 3 to 2. 9 ng / g, respectively. The average recoveries of 7 OPEs in different matrices ( dust and soil) at two spiked concentration levels ranged from 67. 9% to 117. 4% . The proposed method was successfully applied to detect OPEs in different environmental matrices collected in Shanghai.
