Simultaneous Determination of Catechol and Hydroquinone at Electrospun Palladium Nanoparticle/Carbon Nanofibers Modified Electrode
- VernacularTitle:钯/碳纳米纤维复合材料修饰电极同时检测邻苯二酚和对苯二酚
- Author:
Haijiang ZHANG
;
Chunyan WANG
;
Jianshe HUANG
;
Tianyan YOU
- Publication Type:Journal Article
- Keywords:
Electrospinning technique;
palladium nanoparticle/carbon nanofibers;
catechol;
hydroquinone;
simultaneous determination
- From:
Chinese Journal of Analytical Chemistry
2009;37(11):1622-1626
- CountryChina
- Language:Chinese
-
Abstract:
Palladium nanoparticle/carbon nanofibers(Pd/CNFs) were prepared by electrospinning technique with subsequent thermal treatments and were employed to modify glassy carbon electrode (Pd/CNF-GCE/ CME). Pd/CNF-GCE/CME exhibited excellent electrocatalytic activities towards catechol and hydroquinone,and the reversibility of catechol and hydroquinone were significantly improved. The effects of pH value on the oxidation peak current and potential of catechol and hydroquinone were studied by differential pulse voltamme-try(DPV),and 0. 1 mol/L PBS(pH 8.0) was selected as the supporting electrolyte. Under the optimized conditions,the oxidation peak current of catechol was linearly with the concentration of catechol in the range of 1-90μmol/L in the presence of 50 μmol/L hydroquinone with the detection limit of 0.3μmol/L(S/V =3) and the oxidation peak current of hydroquinone was linearly with the concentration of hydroquinone in the range of 2 - 100μmol/L in the presence of 50 μmol/L catechol with the detection limit of 1. 0μmol/L. Furthermore,the modified electrode exhibited good reproducibility and selectivity. The modified electrode has been used for the determination of catechol and hydroquinone in imitative water samples with satisfactory results.
