Hydrogenation properties of mechanically milled Mg2Ni0.8Cr0.2-CoO/Al2O3 composites.
- Author:
Xiu-Li WANG
1
;
Jiang-Ping TU
;
Chang-Pin CHEN
;
Xiao-Bin ZHANG
;
Xin-Bing ZHAO
Author Information
1. Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China.
- Publication Type:Journal Article
- MeSH:
Absorption;
Aluminum Oxide;
analysis;
chemistry;
Hot Temperature;
Hydrogen;
analysis;
chemistry;
Kinetics;
Magnesium Compounds;
analysis;
chemistry;
Manufactured Materials;
analysis;
Materials Testing;
Molecular Conformation;
Nitrogen Compounds;
analysis;
chemistry;
Pressure;
Temperature
- From:
Journal of Zhejiang University. Science. B
2005;6(3):208-212
- CountryChina
- Language:English
-
Abstract:
Mg2Ni0.8Cr0.2-x wt.% CoO/Al2O3 (x=0.5, 1, 2 and 3) composites were prepared by mechanically milling sintered Mg2Ni0.8Cr0.2 alloy and CoO/Al2O3 compound for 45 h. The addition of CoO/Al2O3 compound resulted in the good kinetics properties of hydriding/dehydriding reaction of the composites. The composite with 1.0 wt.% CoO/Al2O3 catalyst could reach the maximum hydrogen absorption capacity (2.9 wt.%) within 5 min at 393 K under H2 pressure of 4 MPa, and can desorb rapidly at 493 K. The decomposition and synthesis of hydrogen molecule on Mg2Ni0.8Cr0.2 alloy surface was promoted by addition of CoO/Al2O3 catalyst. In addition, the formation of metallic Ni particles, strain and defects during the ball milling process also resulted in the improved hydrogenation performance of Mg2Ni-based alloys.
