Phenylethanoid glycosides from stem of Chirita longgangensis var. hongyao.
- Author:
Man-Yuan WANG
1
;
Lan YANG
;
You-You TU
Author Information
- Publication Type:Journal Article
- MeSH: Catechols; chemistry; isolation & purification; Coumaric Acids; chemistry; isolation & purification; Disaccharides; chemistry; isolation & purification; Glucosides; chemistry; isolation & purification; Glycosides; chemistry; isolation & purification; Magnoliopsida; chemistry; Plant Stems; chemistry; Plants, Medicinal; chemistry
- From: China Journal of Chinese Materia Medica 2005;30(24):1921-1923
- CountryChina
- Language:Chinese
-
Abstract:
OBJECTIVETo isolate and elucidate the constituents from stem of Chirita longgangensis var. hongyao.
METHODThe constituents were extracted with methanol and isolated by chromatography on silica gel, Sephadex LH-20 and ODS. The structures were determined by NMR and MS spectral analysis.
RESULTFive phenylethanoid glycosides were identified as 3, 4-dihydroxyphenyl alcohol-beta-D-glucopyranoside (1), 3, 4-dihydroxyphenyl alcohol-6-O-caffeoyl--D-glucopyranoside (calceolarioside B) (2), 3, 4-dihydroxyphenyl alcohol-beta-D-glucopyranosyl-(1 --> 3)-6-O-caffeoyl-beta-D-glucopyranoside (plantainoside D) (3), 3, 4-dihydroxyphenyl alcohol-beta-D-glucopyranosyl-(1 --> 3)-4-O-caffeoyl-beta-D-glucopyranoside (plantamajoside) (4), 3, 4-dihydroxyphenyl alcohol-beta-D-glucopyranosyl-(1 --> 3)-6-O-feruloyl-beta-D-glucopyranoside (scroside E) (5), respectively.
CONCLUSIONCompounds 3 and 5 were isolated for the first time from the family Gesneriaceae, and compounds 1, 2 and 4 were isolated for the first time from the genus Chirita.