Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform.
- Author:
Mokhtar IMIT
;
Takakazu YAMAMOTO
;
Patigul IMIN
- Publication Type:Letter
- MeSH:
Air;
Chloroform;
analysis;
chemistry;
radiation effects;
Kinetics;
Light;
Nitrogen;
chemistry;
Oxygen;
chemistry;
Photochemistry;
methods;
Thiophenes;
analysis;
chemistry;
radiation effects
- From:
Journal of Zhejiang University. Science. B
2005;6(8):722-724
- CountryChina
- Language:English
-
Abstract:
Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform under irradiation with light were studied. The reactions were separately carried out under air, oxygen, and nitrogen. The obtained results showed that this reaction belongs to the pseudo-first-order reaction with a rate constant k(obs) of 1.4 x 10(-5) s(-1) at room temperature. The presence or absence of air, oxygen, and nitrogen did not have obvious effects on the reaction rate under irradiation with light.
