Analysis of Urinary Calculi by X-Ray Diffraction Method.
- Author:
Chul Sung KIM
1
;
Choon Gon KIM
Author Information
1. Department of Urology, College of Medicine, Chosun University, Kwangju, Korea.
- Publication Type:Original Article
- Keywords:
calcium oxalate;
urolithiasis;
analysis;
X-ray diffraction
- MeSH:
Ammonium Compounds;
Calcium;
Calcium Oxalate;
Calculi;
Classification;
Crystallins;
Cystine;
Humans;
Hydrogen;
Kidney Calculi;
Magnesium;
Ureteral Calculi;
Uric Acid;
Urinary Bladder Calculi;
Urinary Calculi*;
Urinary Tract;
Urolithiasis;
Urology;
X-Ray Diffraction*
- From:Korean Journal of Urology
1987;28(2):233-245
- CountryRepublic of Korea
- Language:Korean
-
Abstract:
The analysis of urinary calculi is an essential step in the examination and initial treatment of the patient with urolithiasis. Among the various methods of stone analysis, we have used x-ray diffraction method for analyzing urinary calculi. The advantage of x-ray diffraction is its almost absolute identification of crystalline materials and mixtures of crystalline materials. The disadvantage of x-ray diffraction include initial high cost of equipment and inability to identify amorphous materials and constituents present in only minor or trace amounts. We have analyzed 127 urinary calculi by x-ray diffraction method, which were obtained from the patients who were admitted to the Department of Urology, Chosun University Hospital during the period of 5 years from Jan. l98l to Dec. l985. The following results were obtained: 1. In this studies, 8 crystalline components of urinary calculi were demonstrated: Calcium oxalate monohydrate, Calcium oxalate dehydrate, Calcium oxalate trihydrate, Hydroxyl-apatite, Magnesium ammonium phosphate hexahydrate, Calcium hydrogen phosphate dihydrate, Uric acid and Cystine. 2. Calculi of single component, comprising 73 (57.6%) of the total, was more common than those of mixed component, 54 (42.4%) of the total. Calcium oxalate monohydrate was the most common pure calculi, composing 46 (36.2 %) of all pure calculi and mixed calcium oxalate monohydratecalcium oxalate dihydrate calculi was the most common mixed calculi, constituting 20 (15.7%) of all mixed Calculi. 3. Classifying author`s results as Jensen`s classification, pure calcium oxalate and calcium oxalate apatite mixtures composed 87.3% of total, magnesium ammonium phosphate-apatite mixtures constituted 4.O%, uric acid comprised 6.5%. 4. Among the all urinary components analyzed in this studies, calcium oxalate monohydrate was the most common constituent, composing 78% of the total and calcium oxalate dihydrate was the second common constituent, comprising 37.6%, calcium oxalate was the most common component, composing 9l.3% of the total. 5. In the components associated with calcium oxalate monohydrate, calcium oxalate dihydrate was the most common associated component, in calcium oxalate dihydrate calcium oxalate monohydrate, in hydroxyl-apatite calcium oxalate monohydrate, in uric acid calcium oxalate monohydrate 6. According to the distribution of urinary component in each urinary organ, calcium oxalate (esp. calcium oxalate monohydrate exceeded 50%) was the most common component in entire urinary tract, which comprised 59.1% of all renal calculi, 69.4% of all ureteral calculi, 33.3% of all bladder calculi and 100% of all urethral calculi. 7. Of 44 renal calculi, 30 were composed of staghorn calculi, in which calcium oxalate was the most common component, constituting 56.6% of 30 staghorn calculi.
