Carbon Nanotubes Self-Interlacing Transmission Electron Microscopy Grids for Electrodeposition Characterizations in Batteries
10.19756/j.issn.0253-3820.221294
- VernacularTitle:碳纳米管自交织薄膜载网的构建及用于电池中的沉积分析
- Author:
Fang CHEN
1
;
Wei-Dong ZHANG
;
Ze-Yu SHEN
;
Ying-Ying LU
Author Information
1. 浙江大学化学系,杭州 310027
- Keywords:
Carbon nanotubes;
Grid;
Electrodeposition;
Scanning electron microscopy;
Transmission electron microscopy
- From:
Chinese Journal of Analytical Chemistry
2024;52(7):1012-1019
- CountryChina
- Language:Chinese
-
Abstract:
Transmission electron microscopy(TEM)is considered as an important characterization tool for revealing morphology of materials and an indispensable strategy for studying the mechanisms of charge-discharge process in battery.TEM samples needs be less than 0.1 μm thick,which means electrodeposited materials must undergo pre-treatment processes such as focusing ion beam etching,ultra-thin slicing,or ultrasonic dispersion before they can be observed via TEM.However,such treatments cause structure changes,and what real formed in electrodes is hard to estimate.In this work,a self-interlacing film layer composed of carbon nanotubes(CNTs)was fabricated on a copper grid through blade coating.A novel TEM grid was produced by optimizing the interlacing film's thickness and covering area through adjusting the interlacing state of various concentrations of CNTs.Utilizing the novel TEM grid as the battery's positive electrode,electrode deposits were acquired and subjected to TEM analysis to generate high-definition microstructure images of the electrode surface.This process provided new insights into sample preparation for investigating the deposition/stripping mechanism in high-energy-density metal anodes.
